Boiler passivation procedure pdf merge

Experimental procedure chemicals used for cleaning operation were hydrazine hydrate 64 % russia ori gi n, sulphuric. The vgb guideline preservation of power plants is a summary of existing and revised literature on preservation methods according to the stateoftheart. Tanis, procedures of industrial water treatment, ltan inc. The pitting corrosion leads to boiler tube failures and might damage. Fill the boiler completely to the stop valve with softened, and if possible deaerated, water that is treated with catalyzed sodium sulphite and caustic soda.

Passivation of stainless steel is a process that removes free iron from the surface of a stainless component and at the same time promotes the formation of a thin, dense oxide protective barrier. The manufacturing process of the boilers is clearly a dirty process, and there is a large risk that the boilers will be contaminated with millscale,oils, or slag from the manufacture of the boiler. Chemical clean, passivation new boiler cleaning pipe work. Proper commissioning and initial startup procedures extend. Boiler passivation wholesale, passivation suppliers alibaba. Passivation is the name applied to a number of different processes related to stainless steel.

Edta cleaning processalkali flushing procedure alkali flushing alkali solution made by adding tsp0. Grinding to remove weld spatter and smooth out scratches. Cn102586772b passivation process after chemical cleaning. The process comprises preparing a passivation solution, and adding the passivation solution after the cleaning of the boiler is passed, and circulating at 1535 deg c for 812 hours, wherein the passivation solution comprises methanol, sodium hydrogen sulfate, hydrazine, trialkyl ammonium chloride, ammonia and water, the contents of the above components in per liter of the passivation solution are as follows. One can reference industry standards astm a380 and astm a967 for guidance on the procedure to be followed. Alternatively, when it concerns the water side of a system, the passive film formed will be a good basis for the boiler water treatment programme. During fabrication and erection of the pressure parts, some amount of oil and lubricants can also. Steam blowing of supercritical thermal power plant 2x800. Jim robinson senior boiler consultant, trevose, pa ed baumgartner senior project sales, spokane, wa. When boiler goes back on line, check areas for steam. In the case of edta, passivation occurs after cooling the boiler to 160f and after the. This passive layer gets damaged through heat or chemical damage due to high humidity levels.

Passivation is the process of forming a passive layer of chromium oxide on the surface of stainless steel to protect it from corrosion. Carbonate and bicarbonate alkalinities can combine with calcium and. Proper commissioning and initial startup procedures extend boiler life. Boiler water treatment association of water technologies. I want to know in boiler passination and boil out the. The total iron content shall not exceed 150 gm as fe in 1 liters of the cleaning solution. Hplc passivation procedure for sensitive applications like e. Acid cleaning operation for a natural circulation high pressure drum boiler unit of a thermal power station. Before a boiler is put into service, it is customary to follow a precommissional chemical cleaning procedure. The ferric iron content of the cleaning solution shall be monitored to avoid the attack on the metal. Unless otherwise specified, passivation in the present context is the chemical treatment of a stainless steel with a mild oxidant so as to remove free iron from the surface and speed up the process of forming a protectivepassive layer. Added costs grow rapidly with no or poorly applied chemical cleanings. A number in parentheses indicates the year of last.

Stainless steel is able to resist corrosion thanks to a passive chromium oxide layer that forms on its surface. Boiler boil out and passivation posted in refining, hydrocarbons, oil, and gas. Steam boiler alkali boil out procedure boilersinfo. In the case of hcl, passivation is preceded by rinses and neutralization of any remaining acid in the boiler. Pdf analysis of the acid passivation of stainless steel. The reference for passivation of stainless steel is astm a967. Fill the boiler with demiwater and supply steam until temperatures reaches to. Boiler water treatment principles and practice, volume 1.

The initial cleaning of a new boiler or pipework is critical to its operational success. This will extend the life of the vessel by protecting it from corrosion. Nalco 77262 is designed to assure a high level of cleanliness in the boiler system, especially on the heat transfer surfaces, together with a complete corrosion inhibiting action. Why recommend ammoniated citric acid for the chemical. Evaluation of boiler chemical cleaning techniques inis. The role of citric acid as a surface passive has been reported in stainless steel processing 25, 26 where it provides a more environmentally friendly and safer passivation treatment compared with. Passivation is the process of treating the metal with acids in order to remove the free iron from the surface of the metal and coat it with this corrosionpreventing oxide layer. Banes, astro pak corporation to insure having the maximum corrosion resistance that austenitic stainless steel has to offer, the stainless steel surface must be in a passive state. In order to carry out a thorough passivation, the boiler should be chemically clean.

On section 3 boiler fouling build up due to metal load will be described and analyzed. Chemical cleaning is a multiple stage process that seeks to remove all the existing scale from the boiler internals, leaving a clean, passivated waterside system. A thorough rinsing with fresh water, preferably using. New developments in passivation technology have proceeded in two different areas. Pdf preoperational cleaning requirements for hrsg units. The first of these new developments is the improvement in chemistry for the removal of surface contaminants and the second is the employment of advanced instrumental techniques to measure the passive layer. Index foreword 1 1 stainless steel and the need for cleaning 2 1.

A discussion started in 2001 but continuing through 2019. Economizer corrosion control involves procedures similar to those employed for. This is done by adding a chemical that removes free iron and allows chromium oxide to form. Avestapolarit welding pickling handbook handbook for the pickling and cleaning of stainless steel. Abrasion or excessive heat caused by welding will destroy this protective layer and expose the metal to corrosion. Why passivate stainless steel and what happens if you dont. Sh outlet pressure sh outlet temperature feed water temperature at eco inlet maximum continuous rating 155 kgcm2 540 0 c 247 0 c 865 th water holding capacity. Mechanical cleaning and water flushing can remove loose scale and other debris from the boiler through wiping, brushing, blowing, and friction method. If steam is not going to certain areas check steam lines for water and drain. Patchy, uneven pickled surfaces can result if surfaces are not clean before the acid treatment. Learn more about industrial boiler water treatment, causes and types of boiler. A twostep procedure can provide the best possible corrosion resistance. Back to startup back to onsite services chemical clean and passivation.

How do i passivate stainless steel parts after machining operations. The boiler is lighted up and pressured is raised to 40 kg per cm2 the sample is to be tested for hydrazine concentration and should not be less than 25 ppm after 24 hours fire should be killed and boxed up open super heater vent at 90c and boiler is drained, the second stage passivation marks completion of chemical cleaning 8 passivation. Standard practice for cleaning, descaling, and passivation. It is a systematic procedure used after completion of erection in making the boiler and its auxiliaries available for safe, smooth and reliable operation. Mud or bottom blowdown is usually a manual procedure done for a few seconds on intervals. During manufacturing seamless steel tubes, mill scales are bound to be formed, and some of these can remain inside. After passivation, various tests can be performed to verify whether passivation has been properly performed. Proper boiler water treatment is the key to a successful steam boiler startup and.

Boiler boil out and passivation refining, hydrocarbons. These are common questions asked by machining shops and manufacturers of various part materials. Boiler inspections are dirty, usually hot and wet, confining and always a humbling experience, but they are absolutely essential. The limits for iron and ferric iron shall not exceed 0.

Passivation of mild steel boiler tubes august 22, 2016. Sufficient disodium phosphate must be available to combine with all of the. Refer to section 15185 for a complete list of sections related to chemical cleaning and treatment of mechanical systems. Boilout procedure watertube steam boilers preface the internal surfaces of a newly installed boiler may be contaminated with oil, grease or other protective coatings used in the manufacturing process.

Nalco 77262 can be applied in low pressure boiler systems without deaerator and on softened feedwater makeup with a total feedwater. A newly constructed boiler will be contaminated by particulate debris, oils and greases, and rust. Steam boiler boilouts passivation boiler and pressure. If these products are not removed, corrosion will occur. Acid cleaning operation for a natural circulation high. One step in the process involves the use of inhibited acid to dissolve the scales. While the inertness of surfaces in the flow path is very good and the level of elution of metal ions from agilent hplc systems is. Ss passivating chemicals are domestically available, and these are used by circulating within the ss pipelines and boiler. Use of ammoniated citric acid for the chemical cleaning of high pressure boilers. Such coatings must be removed since they reduce the heat transfer. In the boiler furnace, the chemical energy in the fuel is converted into heat, and it is the function of the boiler to transfer this heat to the contained water in the most efficient manner. Boiler water treatment introduction a boiler is a closed vessel in which water under pressure is transformed into steam by the application of heat. Passivation of stainless steel vessels for boilers is a recommended practice. Passivation is designed to maximize the inherent corrosion resistance of stainless steel parts after machining.

Is there any hplc passivation procedure available for. The formation of this protective layer is called passivation. Passivation of stainless steel astm a967, qqp35, ams 2700. Pickling and passivating stainless steel light scaling left on weld caps and heat tint on the surrounding parent tube surfaces can usually be removed by acid pickling. The cleaning mechanism and passivation on clean surface of tubes by circulation of 500 mg l1. My understanding is that the alkali boil out procedure alone cannot remove the rust, mill scale, etc.

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